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aquifer recharge zone in this dolomitic aquifer) to Na-Cl facies (samples from wells near the coast) 444 Tracking mass balances along groundwater ow-paths Given the wide range of processes which affect groundwater quality evolution (evaporation, mineral dissolution/precipitation, sorption, mixing, etc), it might seem unlikely that we would be able to make much progress in unravelling the evolutionary history of a given groundwater However, as the trends plotted on Figure 47 reveal, some trends in groundwater quality evolution can be relatively easy to identify Even for more complex cases, it is possible to develop models which can quantitatively explain the differences in chemical composition between two water samples at either end of a given ow path within an aquifer.

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Given our knowledge of the chemical composition of the common rockforming minerals, coupled with insights into the processes of cation exchange, it is possible to construct plausible explanations for changes in the molar concentrations of given solutes as water migrates from one point to another For instance, in a limestone aquifer, in which the principal rock-forming mineral is invariably calcite (CaCO3), it is reasonable to infer that an observed increase in dissolved Ca2+ concentrations between an up-gradient and down-gradient well located along the same ow path can be ascribed to dissolution of calcite Using molar concentrations and recalling that one mole of any substance has a mass in grams which is equal in numerical value to its relative molecular mass (Box 4.

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1), we can go on to calculate how many grams of calcite must have dissolved in each liter of groundwater to explain the observed rise in dissolved Ca2+ between the two wells Such a model is known as a geochemical mass balance model One common application of geochemical mass balance modeling is the deduction of the processes which occur during the transformation of rainwater into groundwater (eg Chen et al 1999; Younger 2004a) Such studies have a number of uses For instance, they can help to.

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